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Accueil > Recherche > Publications / brevets > Publications équipe ENSEMBLE > Publications Moléc nanomat fluo > Publications BODIPY

N-Vinyl Ferrocenophane Pyrrole: Synthesis and Physical and Chemical Properties

O. Galangau, C. Dumas-Verdes, E. Y. Schmidt, B. A. Trofimov and G. Clavier Organometallics, 2011, 30, 23, 6476-6481

Références :

Organometallics, 2011, 30, 23, 6476-6481

Auteur(s) : 

O. Galangau, C. Dumas-Verdes, E. Y. Schmidt, B. A. Trofimov and G. Clavier







A new synthesis of [3]ferrocenophan-1-one has been developed, and a Trofimov reaction has been applied to its ketoxime. The novel subsequent N-vinyl pyrrole ferrocenophane displays reversible electrochemical behavior centered on the ferrocene, without any participation of the pyrrole. Unexpected byproduct was also isolated, in which the α-pyrrolic position is methylated.




Type :
Publication
Dates :
Paru le 16 novembre 2011
Informations complémentaires :
DOI: 10.1021/om200839b

 

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