Accès direct au contenu

PPSM

Version anglaise

aide

Accueil > Recherche > Publications / brevets > Publications équipe ENSEMBLE > Publications Moléc nanomat fluo

Tetracyano isoindigo small molecules and their use in n-channel organic field-effect transistors

Dasari, RR; Dindar, A; Lo, CK; Wang, CY; Quinton, C; Singh, S; Barlow, S; Fuentes-Hernandez, C; Reynolds, JR; Kippelen, B; Marder, SR PHYSICAL CHEMISTRY CHEMICAL PHYSICS 2014, 16, 19345-19350.

Références :

PHYSICAL CHEMISTRY CHEMICAL PHYSICS 2014, 16, 19345-19350.

Auteur(s) : 

Dasari, RR; Dindar, A; Lo, CK; Wang, CY; Quinton, C; Singh, S; Barlow, S; Fuentes-Hernandez, C; Reynolds, JR; Kippelen, B; Marder, SR

N,N'-Dihexyl-6,6'-dicyanoisoindigo, N,N'-didecyl-5,5',6,6'-tetracyanoisoindigo, N,N'-dihexyl-5,5',6,6'-tetracyanoisoindigo, and N,N'-dihexyl-5,5',6,6'-tetracyanothienoisoindigo have been synthesised in moderate yields by the reaction of corresponding di and tetrabromo species with CuCN, with microwave heating leading to higher yields and fewer side products for the tetrasubstituted species. Di- and tetracyano substitution anodically shifts the molecular reduction potential relative to the unsubstituted cores by ca. 0.4 and 0.8 V, respectively, with the resultant values for the tetracyano derivatives (-0.58 to -0.67 V vs. FeCp2+/0) suggesting the possibility of air-stable electron transport. All the synthesised cyano derivatives operate in n-channel OFETs, while the tetrabromothienoisoindigo derivative functions in a p-channel transistor. The tetracyanothienoisoindigo derivative exhibits the highest field-effect electron mobility values - up to 0.04 and 0.09 cm(2) V-1 s(-1) in spin-coated and inkjet-printed devices respectively - and OFETs incorporating this compound have been shown to operate in air without significant degradation of their mobility values in the saturation regime.

Illustration Article Dassari
Type :
Publication
Dates :
Paru le 7 août 2014
Informations complémentaires :

DOI: 10.1039/c4cp02427c


 

Publications antérieures 

2015
2014
2013
2012
2011
2010
2009
2008
2007

Recherche d'un document

Recherche d'un document