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Photoinduced Multielectron Transfer to a Multicopper Oxidase Resulting in Dioxygen reduction into water

J. A. Simaan, Y. Mekmouche, C. Herrero, P. Moreno, A. Aukauloo, J. A. Delaire, M. Réglier and T. Tron, Chemistry – A European Journal, 2011, 17, 42, 11743-11746

Références :

Chemistry – A European Journal, 2011, 17, 42, 11743-11746

Auteur(s) : 

J. A. Simaan, Y. Mekmouche, C. Herrero, P. Moreno, A. Aukauloo, J. A. Delaire, M. Réglier and T. Tron





Dioxygen reduction: The photoinjection of four electrons into a multicopper oxidase is described for the first time. In the presence of an exogenous electron donor and a photosensitizer, the enzyme can be fully reduced and is in turn able to reduce dioxygen to water.




Type :
Publication
Dates :
Paru le 6 septembre 2011
Informations complémentaires :
DOI: 10.1002/chem.201101282

 

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