Publications

ou physique

Maximizing Chiral Perturbation on Thermally Activated Delayed Fluorescence Emitters and Elaboration of the First Top‐Emission Circularly Polarized OLED

Molecular designs merging circularly polarized luminescence (CPL) and thermally activated delayed fluorescence (CP-TADF) using the concept of chiral perturbation appeared recently as a cornerstone for the development of efficient CP-organic light…

Lucas Frédéric, Alaric Desmarchelier, Romain Plais, Leonid Lavnevich, Gilles Muller, Cassie Villafuerte, Gilles Clavier, Etienne Quesnel, Benoit Racine, Sylvia Meunier‐della‐gatta, Jean‐pierre Dognon, Pierre Thuéry, Jeanne Crassous, Ludovic Favereau, Grégory Pieters

Advanced Functional Materials - 2020

Chimie

Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO2 Reduction

The Keggin-type polyoxometalate (POM) PW12O403– and the catalytic complex Cp*Rh(bpydc)Cl2 (bpydc = 2,2′-bipyridine-5,5′-dicarboxylic acid) were coimmobilized in the Zr(IV) based metal organic framework UiO-67. The POM is encapsulated within the…

Youven Benseghir, Alex Lemarchand, Mathis Duguet, Pierre Mialane, Maria Gomez-Mingot, Catherine Roch-Marchal, Thomas Pino, Minh-Huong Ha-Thi, Mohamed Haouas, Marc Fontecave, Anne Dolbecq, Capucine Sassoye, Caroline Mellot-Draznieks

Journal of the American Chemical Society - 2020

ou physique

Time-resolved fluorescence microscopy combined to Scanning ElectroChemical Microscopy (SECM): a new way to visualize photo-induced electron transfer quenching with an electrofluorochromic probe

The combination of Scanning Electrochemical Microscopy (SECM) and Time-Resolved Fluorescence Microscopy was successfully implemented to investigate the control of the fluorescence of a tetrazine derivative in solution according to its redox state, a…

Laetitia Guerret-Legras, Jean-Frédéric Audibert, Indra M Gonzalez Ojeda, Galina Dubacheva, Gilles Clavier, Fabien Miomandre

Journal of Physical Chemistry C - 2020

Chimie

Layer-by-layer functionalization of gold nanorods by polyelectrolytes to control surface spacer and precisely tune the surface plasmon resonance position

Céline Jégat, Guillaume Laurent

Chemistry Letters - 2020

Chimie organique

Luminescent molecular switches based on dicationic P-doped Polycyclic Aromatic Hydrocarbons

We report the efficient synthesis of electron-acceptors based on cationic P-doped polycyclic aromatic hydrocarbons. In particular, exo-skeletal modifications of the p-core were performed and their effect on the optical and redox properties was…

Thomas Delouche, Antoine Vacher, Thierry Roisnel, Marie Cordier, Jean-Frédéric Audibert, Boris Le Guennic, Fabien Miomandre, Denis Jacquemin, Muriel Hissler, Pierre-Antoine Bouit

Materials Advances - 2020

Héritage culturel et muséologie

In-place molecular preservation of cellulose in 5,000-year-old archaeological textiles

The understanding of fossilization mechanisms at the nanoscale remains extremely challenging despite its fundamental interest and its implications for paleontology, archaeology, geoscience, and environmental and material sciences. The mineralization…

Corentin Reynaud, Mathieu Thoury, Alexandre Dazzi, Gael Latour, Mario Scheel, Jiayi Li, Ariane Thomas, Christophe Moulherat, Aurore Didier, Loïc Bertrand

Proceedings of the National Academy of Sciences of the United States of America - 2020

ou physique

Exciton Interactions, Excimer Formation, and [2π+2π] Photodimerization in Nonconjugated Curcuminoid‐BF 2 Dimers

We describe the synthesis of a series of covalently linked dimers of quadrupolar curcuminoid‐BF2 dyes and the detailed investigation of their solvent‐dependent spectroscopic and photophysical properties. In solvents of low polarity, intramolecular…

Manon Catherin, Olatz F Uranga-Barandiaran, Arnaud Brosseau, Rémi Métivier, Gabriel Canard, Anthony d'Aléo, David Casanova, Frederic Castet, Elena Zaborova, Frédéric Fages

Chemistry - A European Journal - 2020

Chimie organique

Donor-acceptor 1,2,4,5-Tetrazines Prepared by Buchwald-Hartwig Cross-Coupling Reaction and Their Photoluminescence Turn-on Property by Inverse Electron Demand Diels-Alder Reaction

A facile efficient synthetic tool, Buchwald-Hartwig cross-coupling reaction, for the functionalization of 1,2,4,5tetrazines is presented. Important factors affecting the Buchwald-Hartwig cross-coupling reaction have been optimized. Seven new donor…

Yangyang Qu, Piotr Pander, Oleh Vybornyi, Marharyta Vasylieva, Régis Guillot, Fabien Miomandre, Fernando B Dias, Peter Skabara, Przemyslaw Data, Gilles Clavier, Pierre Audebert

Journal of Organic Chemistry - 2020

Microélectronique

Chimie des Matériaux pour l’optoélectronique imprimée

Pierre Audebert, Johann Bouclé

Lettre XLIM - 2020

Physique

A new Devonian euthycarcinoid reveals the use of different respiratory strategies during the marine-to-terrestrial transition in the myriapod lineage

Myriapods were, together with arachnids, the earliest animals to occupy terrestrial ecosystems, by at least the Silurian. The origin of myriapods and their land colonization have long remained puzzling until euthycarcinoids, an extinct group of…

Pierre Gueriau, James Lamsdell, Roy Wogelius, Phillip Manning, Victoria Egerton, Uwe Bergmann, Loïc Bertrand, Julien Denayer

Royal Society Open Science - 2020