Publications

Chimie

Perylene based PET fluorescent molecular probes for pH monitoring

New perylene-based pH probes have been synthesized and utilized for the development of pH optodes. These amine-functionalized perylene-based probes display high molar absorption coefficients in the visible range and protonated forms are…

Ayedah Tariq, Ulysse Garnier, Rasta Ghasemi, Jean Pierre Lefevre, Cédric Mongin, Arnaud Brosseau, Jean Frédéric Audibert, Robert Pansu, Alexandre Dauzères, Isabelle Leray

Journal of Photochemistry and Photobiology A: Chemistry - 2022

Héritage culturel et muséologie

Microchemical Imaging of Oil Paint Composition and Degradation: State-of-the-Art and Future Prospects

Oil paint is a dynamic system that undergoes chemical alteration on several time and length scales. At the short term, curing reactions are necessary for oil to dry properly. At longer time scales, a wide variety of other chemical processes can…

Selwin Hageraats, Mathieu Thoury, Marine Cotte, Loïc Bertrand, Koen Janssens, Katrien Keune

Analytical Chemistry for the Study of Paintings and the Detection of Forgeries - 2022

Chimie organique

On the road for more efficient biocompatible two-photon excitable fluorophores

Red to NIR absorption and emission wavelengths are key requirements for intravital bioimaging. One of the way to reach such excitation wavelengths is to use two-photon excitation. Unfortunately, there is still a lack of two-photon excitable…

Marie Auvray, Frédéric Bolze, Delphine Naud-Martin, Matthieu Poulain, Margaux Bossuat, Gilles Clavier, Florence Mahuteau-Betzer

Chemistry - A European Journal - 2022

Statistiques

Politique de Science Ouverte du DIM Patrimoines matériels - Innovation, expérimentation et résilience

Caroline Corbières, Loïc Bertrand, Serge X. Cohen, Sophie David, Laurent Romary

Polymères

Trialkoxyheptazine-Based Glyconanoparticles for Fluorescence in Aqueous Solutions and on Surfaces via Controlled Binding in Space

The fluorescent organic 2,5,8-tris((adamantan-1-yl) methoxy)-heptazine (HTZ-Ad) was solubilized in water by inclusion of adamantane groups into free β-cyclodextrins or cyclodextrin shell of glyconanoparticles. These glyconanoparticles with average…

Monica Brachi, Paulo Henrique M. Buzzetti, Karine Gorgy, Dan Shan, Pierre Audebert, Alan Le Goff, Hong Li, R. Borsali, Serge Cosnier

ACS Macro Letters - 2022

Chimie de coordination

Visible‐Light‐Initiated Palladium‐Catalyzed Cross‐coupling by PPh3 Uncaging from an Azobenzene Ruthenium–Arene Complex

Triphenylphosphine photo-release from a sulfonamide azobenzene ruthenium-arene complex was exploited to activate Pd(II)Cl2 into Pd(0) catalyst, for the photo-initiation of Sonogashira cross-couplings. The transformation was initiated on demand –…

Lou Rocard, Jérôme Hannedouche, Nicolas Bogliotti

Chemistry - A European Journal - 2022

Chimie organique

Synthesis and Spectroscopic Characterization of Novel Thiourea-Bearing Photoactivatable NADPH Mimics Targeting NO Synthases

Abstract A new set of photoactivatable NADPH mimics bearing a thiourea linkage between a diarylbutadiene and an adenosine moiety functionalized by O-carboxymethyl groups has been designed and synthesized in a convergent strategy. These compounds…

Clément Polese, Eric Deprez, Patrick Tauc, Nicolas Bogliotti, Juan Xie

Synthesis: Journal of Synthetic Organic Chemistry - 2022

ou physique

4,4’-Dimethylazobenzene as a Chemical Actinometer

Chemical actinometers are a useful tool in photochemistry, which allows to measure the photon flux of a light source to carry out quantitative analysis on photoreactions. The most commonly employed actinometers so far show minor drawbacks, such as…

Lorenzo Casimiro, Leonardo Andreoni, Jessica Groppi, Alberto Credi, Rémi Métivier, Serena Silvi

Photochemical & Photobiological Sciences - 2022

Chimie analytique, Art et histoire de l'art

Carbonation of fresco mural paintings with a dolomitic mortar

Núria Oriols, Nati Salvadó, Trinitat Pradell, Núria Jiménez, Marine Cotte, Victor Gonzalez, Salvador Butí

Cement and Concrete Research - 2022

Héritage culturel et muséologie

Application of Synchrotron Radiation-Based Micro-Analysis on Cadmium Yellows in Pablo Picasso's Femme

The cultural heritage community is increasingly exploring synchrotron radiation (SR) based techniques for the study of art and archaeological objects. When considering heterogeneous and complex micro-samples, such as those from paintings, the…

Marta Ghirardello, Victor Gonzalez, Letizia Monico, Austin Nevin, Douglas Maclennan, Catherine Schmidt Patterson, Manfred Burghammer, Matthieu Réfrégiers, Daniela Comelli, Marine Cotte

Microscopy and Microanalysis - 2022