Publications

Chimie

Is it possible to ”simply” predict the photoejection of a cation? Example of azacrown-substituted [(bpy)Re(CO) 3 L] + complexes

In the context of designing efficient photocontrolled ion-release systems, we propose a "simple" computational strategy able to predict the cation photoejection. Our strategy is based on TD-DFT calculations and the analysis of the charge transfer …

Laure de Thieulloy, Clément Barois, Cédric Mongin, Isabelle Leray, Clément Guerrin, Stéphane Aloïse, Guy Buntinx, Aurelie Perrier

Journal of Photochemistry and Photobiology A: Chemistry - 2022

ou physique

Novel D–A chromophores with condensed 1,2,4-triazine system simultaneously display thermally activated delayed fluorescence and crystallization-induced phosphorescence

A new triazine acceptor unit is prepared and investigated together with common donors in D–A materials. With carbazole donors, changes in environment are able to elicit highly varied delayed emission behaviour.

Antonio Maggiore, Xiaofeng Tan, Arnaud Brosseau, Andrew Danos, Fabien Miomandre, Andrew Monkman, Pierre Audebert, Gilles Clavier

Physical Chemistry Chemical Physics - 2022

Chimie

Is it possible to maintain photomechanical properties of crystalline diarylethenes after thermal amorphization?

The photomechanical properties of the photochromic 1,2-bis(2,4-dimethyl-5-phenyl-3thienyl)perfluorocyclopentene (DTE) crystals, largely documented since the discovery by Irie et al. of its reversible photoswitching of crystallographic plane…

Maroua Louati, Sophie Barrau, Jean-François Tahon, Arnaud Brosseau, Marumi Takao, Michinori Takeshita, Rémi Métivier, Guy Buntinx, Stéphane Aloise

Journal of Molecular Structure - 2022

Chimie organique

Mechanofluorochromic Material toward a Recoverable Microscale Force Sensor

in optical properties upon application of mechanical stimuli such as scratching or grinding, promises applications for force sensors. [20-36] Emission changes of coordi nation complex crystals, [24] polymeric micro crystals, [30] and organic…

Jan Patrick Calupitan, Arnaud Brosseau, Pierre Josse, Clément Cabanetos, Jean Roncali, Rémi Métivier, Clémence Allain

Advanced Materials Interfaces - 2022

ou physique

Mechanofluorochromic Difluoroboron <i>β</i> ‐Diketonates Based Polymer Composites: Toward Multi‐Stimuli Responsive Mechanical Stress Probes

Developing mechano-responsive fluorescent polymers that exhibit distinct responses to distinct mechanical stresses requires a careful design of the fluorophore in order to tune its interactions with the polymer. A series of mechanofluorochromic (MFC…

Benjamin Poggi, Elliot Lopez, Rémi Métivier, Laurence Bodelot, Clémence Allain

Macromolecular Rapid Communications - 2022

ou physique

Novel Easy to Synthesize Benzonitrile Compounds with Mixed Carbazole and Phenoxazine Substituents Exhibiting Dual Emission and TADF Properties

The photophysical and electrochemical properties of a new class of fluorinated benzonitrile compounds substituted with mixed phenoxazine and carbazole units have been investigated. When absorbing in a large range of the UV−vis spectrum due to both…

Antonio Maggiore, Yangyang Qu, Régis Guillot, Piotr Pander, Marharyta Vasylieva, Przemyslaw Data, Fernando Dias, Pierre Audebert, Gilles Clavier, Fabien Miomandre

Journal of Physical Chemistry B - 2022

Physique

Tunable Naphthalimide/Cinnoline‐Fused (CinNapht) Hybrid Dyes for Fluorescence Imaging in Living Cells

Minh‐duc Hoang, Farah Savina, Philippe Durand, Pr. Rachel Méallet-Renault, Gilles Clavier, Arnaud Chevalier

ChemPhotoChem - 2022

Autre

Synthèse et propriétés de complexes arène-ruthénium(II) comportant des ligands photocommutables dérivés de l’azobenzène

La manipulation de systèmes moléculaires par la lumière se révèle aujourd’hui comme une stratégie incontournable pour le contrôle spatial et temporel d’évènements à différentes échelles, conduisant à des systèmes « intelligents » aux applications…

Jonathan Long

Imagerie

Biocompatible and Photostable Photoacoustic Contrast Agents as Nanoparticles Based on Bodipy Scaffold and Polylactide Polymers: Synthesis, Formulation, and In Vivo Evaluation

We have designed a new Bodipy scaffold for efficient in vivo photoacoustic (PA) imaging of nanoparticles commonly used as drug nanovectors. The new dye has an optimized absorption band in the near-infrared window in biological tissue and a low…

Jean-Baptiste Bodin, Jérôme Gateau, Justine Coïs, Théotim Lucas, Flora Lefebvre, Laurence Moine, Magali Noiray, Catherine Cailleau, Stéphanie Denis, Gilles Clavier, Nicolas Tsapis, Rachel Méallet-Renault

ACS Applied Materials & Interfaces - 2022

Polymères

Luminescence-Sensitive Surfaces Bearing Ratiometric Nanoparticles for Bacteria Growth Detection

pH is one of the most fundamental parameters describing the quality of an aqueous solution. We developed a ratiometric fluorescent platform to monitor pH not only in solution but also on surfaces: our nanoprobe is based on fluorescent nanoparticles …

Miaobo Pan, Gabriela Morán Cruz, Chloé Grazon, Djamila Kechkeche, Ludivine Houel Renault, Gilles Clavier, Rachel Méallet-Renault

ACS Applied Polymer Materials - 2022