Publications

Matériaux

De Novo Synthesis of Sugar-Aza-Crown Ethers via a Domino Staudinger Aza-Wittig Reaction

A short and highly efficient route to sugar-aza-crown (SAC) ethers has been developed. The key step of the transformation is a one-pot cyclodimerization of C-glycosyl azido aldehydes via a domino Staudinger aza-Wittig reaction. This process allows…

Mickaël Ménand, Jean-Claude Blais, Jean-Marc Valéry, Juan Xie

Journal of Organic Chemistry - 2006

Radiolytic synthesis and optical properties of ultrasmall stabilized ZnS nanoparticles

ZnS nanoparticles are synthesized by c-irradiation of aqueous solution containing Zn2+ and thiol (RSH). Monodispersed ultra-small ZnS particles with 1.5 nm diameter, characterized by a band edge at 238 nm are produced at low doses. At higher doses,…

A.H. Souici, N. Keghouche, Jacques A. Delaire, H. Remita, M. Mostafavi

Chemical Physics Letters - 2006

Architectures Matérielles

AN ACTIVE CHAOTIC MICROMIXER INTEGRATING THERMAL ACTUATION ASSOCIATING PDMS AND SILICON MICROTECHNOLOGY

Due to scaling laws, in microfluidic, flows are laminar. Consequently, mixing between two liquids is mainly obtained by natural diffusion which may take a long time or equivalently requires centimetre length channels. To reduce time and length for…

Olivier Français, Marie-Caroline Jullien, L. Rousseau, P. Poulichet, Serge Desportes, Assia Chouai, Jean-Pierre Lefèvre, Jacques Delaire

DTIP 2006 - 2006

Chimie inorganique

Polypyridyl ruthenium complexes as coating agent for the formation of gold and silver nanocomposites in different media. Preliminary luminescence and electrochemical studies

Cédric Mayer, Eddy Dumas, Fabien Miomandre, Rachel Méallet-Renault, Fabienne Warmont, Jacky Vigneron, Robert Bernard Pansu, Arnaud Etcheberry, Francis Sécheresse

New Journal of Chemistry - 2006

ou physique

Optically tunable nonlinearities in polymers based on photoisomerizable metal-based coordination complexes

The bottom-up design of polymer films exhibiting quadratic nonlinear optical properties that can be tuned optically and chemically is described. The polymer matrices are doped with metal-containing chromophores built around a Zn-II core and…

Sébastien Bidault, Lydie Viau, Olivier Maury, Sophie Brasselet, Joseph Zyss, Eléna Ishow, Keitaro Nakatani, Hubert Le Bozec

Advanced Functional Materials - 2006

Chimie-Physique

Selective detection of cesium by a water-soluble fluorescent molecular sensor based on a calix[4]arene-bis(crown-6-ether)

Vincent Souchon, Isabelle Leray, Bernard Valeur

Chemical Communications - 2006

Chimie-Physique

Photoisomerizable Bipyridine Ligands and Macroligands: Absorption, Photoisomerization Properties and Theoretical Study

Two 2,2'-bipyridines, substituted at the 4,4'-positions by p-dialkylaminophenylazostyryl moieties p-R2NC6H4N=NC6H4-CH=CH [6a, R2N=nBu2N; 6b, R2N=(nBu)(C4H8OTHP)N; 6c, R2N= (nBu)(C4H8OH)N], were successfully synthesized by using Wadworth- Emmons…

Lydie Viau, Itamar Malkowsky, Karine Costuas, Stéphanie Boulin, Loic Toupet, Eléna Ishow, Keitaro Nakatani, Olivier Maury, Hubert Le Bozec

ChemPhysChem - 2006

Matériaux

Structural and Photoisomerization Cross Studies of Polar Photochromic Monomeric Glasses Forming Surface Relief Gratings

A novel class of photochromic materials based on polar azo derivatives containing functionalized biphenyl substituents has been synthesized. Once melt and cooled, these compounds formed amorphous transparent monomeric materials whose glass…

Eléna Ishow, Bertrand Lebon, Yaning He, Xiaogong Wang, Laurent Bouteiller, Laurent Galmiche, Keitaro Nakatani

Chemistry of Materials - 2006

ou physique

The effect of the conformation on the quadratic nonlinear optical response of metal carbonyl based chromophores with one-dimensional charge transfer capabilities: a computational investigation

The synthesis and the quadratic nonlinear optical (NLO) properties of (4-(4'-dimethylaminophenyl)pyridine)chromium and tungsten pentacarbonyl are reported. Experimentally, the chromophores exhibit molecular hyperpolarizabilities (beta) equal to 15.5…

Jean-François Lamère, Isabelle Sasaki, Pascal G. Lacroix, Keitaro Nakatani

New Journal of Chemistry - 2006

ou physique

Synthesis, characterization and nonlinear optical (NLO) properties of a push-pull bisboronate chromophore with a potential electric field induced NLO switch

A new bisboronate with five six-membered ring heterobicycles was prepared by reaction of [2-(2-hydroxy-4-diethylaminobenzylidene)amino]-5-nitroaminophenol and 1,4-phenyldiboronic acid, and its quadratic nonlinear optical (NLO) response was compared…

Jean François Lamère, Pascal G. Lacroix, Norberto Farfan, Jose Maria Rivera, Rosa Santillan, Keitaro Nakatani

Journal of Materials Chemistry - 2006