Résumé (anglais)
In the last 10 years, there have been a wide variety of studies on thermally activated delayed fluorescence (TADF)-OLEDs focusing on the unlimited possibilities of molecular design [1]. Further, hyperfluorescence (HF)-OLEDs have been developed since they can realize the compatibility of high efficiency and narrow spectral width which is ideal for display applications. The advanced HF-OLEDs realized high light-emitting performance by engineering host, TADF, and terminal emitter (TE) molecules. We mention the comprehensive design principle for the materials and device architectures used in HP-OLEDs by focusing on fast T-S upconversion, negative gap, efficient FRET, GSP, and carrier trapping aimed at high-performance EL [2-5]. In addition, we underscore the crucial role of CT characteristics in organic optoelectronic devices, shedding light on novel devices such as thermoelectrics [6].
References:
[1] T. Uoyama, et al., Nature, 492, 234 (2012)
[2] C.-Y. Chan et al., Nat. Photon., 15, 203 (2021)
[3] Y.-T. Lee et al., Adv. Elect. Mater., 7, 2001090 (2021)
[4] M. Tanaka et al., ACS Appl. Mater. & Inter., 12, 50668 (2020)
[5] Y.-T. Lee et al., Nat. Commun., 15, 3659 (2024)
[6] S. Kondo, et al., Nat. Commun., (in press).