Mixed Copper, Silver, and Gold Cyanides, (MxM '(1-x))CN: Tailoring Chain Structures To Influence Physical Properties

Publié le 3 octobre 2012 - Journal of the American Chemical Society

Auteurs : Ann M. Chippindale, Simon J. Hibble,, Edward J. Bilbe, Elena Marelli, Alex C. Hannon, Clémence Allain, Robert Bernard Pansu, Frantisek Hartl

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Binary mixed-metal variants of the one-dimensional MCN compounds (M = Cu, Ag, and Au) have been prepared and characterized using powder X-ray diffraction, vibrational spectroscopy, and total neutron diffraction. A solid solution with the AgCN structure exists in the (CuxAg1-x)CN system over the range (0